Polypropylene
Polypropylene (PP) is a versatile thermoplastic polymer widely used in packaging, automotive, consumer products, and industrial applications. It is a semi-crystalline polymer with excellent chemical resistance, fatigue resistance, and dimensional stability. Polypropylene is lightweight, durable, and exhibits low moisture absorption, making it ideal for products exposed to humid or wet conditions.
PP is available in homopolymer and copolymer forms (random and impact copolymers), each with slightly different mechanical and thermal properties. It can be extruded, injection molded, thermoformed, or blow molded, allowing for a wide variety of shapes and sizes. Polypropylene also offers good electrical insulation properties and moderate resistance to heat, making it a popular choice in both industrial and consumer applications.
Applications
Chemical Composition
| Component | Carbon (C) | Hydrogen (H) | Additives (optional) |
|---|---|---|---|
| Percentage (%) | ~85% | ~15% | 0–5% |
Hardness
Equivalent Grades
- Country / Region Equivalent Grade / Trade Name
- USA PP-H (Homopolymer), PP-R (Random Copolymer), PP-I (Impact Copolymer)
- Europe (EN / ISO) PP-H, PP-B, PP-R, PP-C (Copolymers)
- Germany (DIN) Moplen® (LyondellBasell), Hostalen® PP, Lupolen®
- Japan (JIS) Himont® PP, Prime Polypropylene (various grades)
- India Polypropylene Homopolymer (PP-H), Random Copolymer (PP-R), Impact Copolymer (PP-I)
- China (GB) PP-H, PP-R, PP-B
- Korea Polypropylene Homopolymer, Random Copolymer, Impact Copolymer
- Global / Trade Names Moplen®, Hostalen®, Lupolen®, Himont®, Prime PP
Heat Treatment
Hardening
Welding
Machinability
Physical Properties
| Property | Value |
|---|---|
| Density | 0.90–0.92 g/cm³ |
| Melting Point | 160–170°C |
| Glass Transition Temperature (Tg) | –10 to 0°C |
| Service Temperature (Continuous) | –20°C to +100°C |
| Tensile Strength | 30–40 MPa (homopolymer), 25–35 MPa (copolymer) |
| Flexural Strength | 40–60 MPa |
| Impact Strength (Notched Izod) | 1.5–3 kJ/m² (homopolymer), 3–6 kJ/m² (impact copolymer) |
| Elongation at Break | 200–600% (copolymer), 50–300% (homopolymer) |
| Shore D Hardness | 55–65 |
| Water Absorption (24 hrs) | ~0.01% |
| Thermal Conductivity | 0.22 W/m·K |
| Coefficient of Linear Expansion | 10–20 × 10⁻⁵ /°C |
| Electrical Resistivity | 10¹³–10¹⁶ Ω·cm |
| Flammability | Self-extinguishing grades available |
Chemical Properties
| Property | Value |
|---|---|
| Acid Resistance | Excellent resistance to weak and strong acids at room temperature. |
| Alkali Resistance | Excellent resistance to mild and strong alkalis. |
| Solvent Resistance | Good resistance to hydrocarbons, alcohols, and ketones; limited resistance to aromatic and chlorinated solvents. |
| Alcohol Resistance | Good; generally stable under exposure to most alcohols. |
| Oxidation Resistance | Fair; may degrade with prolonged exposure to strong oxidizing agents. |
| UV Resistance | Moderate; can degrade under prolonged sunlight unless UV-stabilized grades are used. |
| Weathering Resistance | Good for indoor and short-term outdoor use; stabilized grades suitable for long-term outdoor exposure. |
| Hydrolysis Resistance | Excellent; negligible water absorption prevents dimensional changes. |
| Flammability | Burns slowly; self-extinguishing grades available. |
| Chemical Reactivity | Chemically inert under normal conditions; resistant to many acids, bases, and solvents at moderate temperatures. |