Blogs

Polypropylene

Polypropylene

Polypropylene (PP) is a versatile thermoplastic polymer widely used in packaging, automotive, consumer products, and industrial applications. It is a semi-crystalline polymer with excellent chemical resistance, fatigue resistance, and dimensional stability. Polypropylene is lightweight, durable, and exhibits low moisture absorption, making it ideal for products exposed to humid or wet conditions.

PP is available in homopolymer and copolymer forms (random and impact copolymers), each with slightly different mechanical and thermal properties. It can be extruded, injection molded, thermoformed, or blow molded, allowing for a wide variety of shapes and sizes. Polypropylene also offers good electrical insulation properties and moderate resistance to heat, making it a popular choice in both industrial and consumer applications.

Applications

Polypropylene is widely used in industries due to its chemical resistance, lightweight, and versatility. Common applications include: Packaging: Food containers, bottles, caps, films, and flexible packaging. Automotive Components: Bumpers, dashboards, interior trims, battery cases, and cable insulation. Household Goods: Storage containers, furniture, trays, crates, and kitchenware. Textiles: Ropes, carpets, mats, non-woven fabrics, and disposable medical textiles. Industrial Applications: Pipes, sheets, chemical tanks, and tanks for corrosive liquids. Electrical & Electronics: Insulation for cables, connectors, and components. Medical & Healthcare: Syringes, labware, and packaging for medical devices. Consumer Products: Toys, sports equipment, and furniture parts.

Chemical Composition

Component Carbon (C) Hydrogen (H) Additives (optional)
Percentage (%) ~85% ~15% 0–5%

Hardness

Polypropylene is a moderately soft thermoplastic with hardness dependent on the grade (homopolymer or copolymer) and additives. Shore D Hardness: 55–65 Rockwell Hardness (M Scale): ~65–70 HRM Key Points: Homopolymer PP tends to be slightly harder and more rigid. Impact copolymer grades are softer but offer higher toughness. Hardness is sufficient for packaging, containers, automotive trims, and general engineering applications.

Equivalent Grades

  • Country / Region Equivalent Grade / Trade Name
  • USA PP-H (Homopolymer), PP-R (Random Copolymer), PP-I (Impact Copolymer)
  • Europe (EN / ISO) PP-H, PP-B, PP-R, PP-C (Copolymers)
  • Germany (DIN) Moplen® (LyondellBasell), Hostalen® PP, Lupolen®
  • Japan (JIS) Himont® PP, Prime Polypropylene (various grades)
  • India Polypropylene Homopolymer (PP-H), Random Copolymer (PP-R), Impact Copolymer (PP-I)
  • China (GB) PP-H, PP-R, PP-B
  • Korea Polypropylene Homopolymer, Random Copolymer, Impact Copolymer
  • Global / Trade Names Moplen®, Hostalen®, Lupolen®, Himont®, Prime PP

Heat Treatment

Polypropylene is a thermoplastic polymer, so it does not undergo conventional heat treatment like metals. However, controlled thermal processes are used for stress relief, forming, and dimensional stability. 1. Annealing / Stress Relief PP components may be annealed at 80–100°C to relieve internal stresses caused by molding or machining. Prevents warping, shrinkage, and cracking during service or further processing. 2. Thermoforming Heated to 160–180°C (softening point) for shaping, bending, or forming. After forming, parts are cooled slowly to retain shape. 3. No Hardening Capability Polypropylene cannot be hardened by heat treatment. Mechanical properties are inherent to the polymer type and additives.

Hardening

Polypropylene cannot be hardened through heat treatment, quenching, or conventional metallurgical processes because it is a thermoplastic polymer. Its mechanical properties, including hardness, are determined by: Polymer type: Homopolymer (PP-H) is harder, stiffer; impact copolymer (PP-I) is softer but tougher. Additives: Fillers like glass fibers, talc, or mineral fillers can increase stiffness and surface hardness. Processing conditions: Cooling rate and molding parameters affect crystallinity and dimensional stability, indirectly influencing hardness. Key Point: Any increase in hardness or stiffness must be achieved through material selection, fillers, or copolymerization, not through post-processing.

Welding

Polypropylene can be effectively welded using several plastic welding techniques, making it suitable for tanks, piping, automotive components, and industrial assemblies. Common Welding Methods Hot Gas (Air) Welding Uses a stream of hot air and a PP filler rod. Produces strong, leak-proof joints for sheets, pipes, and molded parts. Hot Plate Welding Surfaces are heated using a hot plate and pressed together. Common for joining large, flat PP components. Ultrasonic Welding High-frequency vibrations generate heat at the joint interface. Ideal for small precision parts and assembly of thin sheets. Spin Welding Parts are rotated under pressure to generate frictional heat. Common for cylindrical or round PP components. Laser Welding (Special Cases) Requires laser-transparent and laser-absorbing parts. Less common but useful in high-precision applications. Limitations Welding parameters must be carefully controlled to avoid burning, bubbling, or warping. Surface contamination, fillers, or additives may affect weld quality.

Machinability

Polypropylene is easily machinable with standard woodworking and metalworking tools, making it suitable for custom parts, prototypes, and industrial components. Key Machining Characteristics Soft and Low Friction Material Cuts, drills, and mills easily without excessive tool wear. Brittleness at Low Temperatures May crack or chip if feed rates are too high or tools are dull. Heat Sensitivity Overheating during cutting can cause melting or deformation. Good Dimensional Stability Maintains tolerances when machined properly; stress relief may be needed for thicker sections. Best Practices Use sharp carbide or HSS tools. Moderate cutting speeds with light feed rates are recommended. Apply air or coolant to prevent thermal deformation. Drill holes using special PP drill bits to avoid chipping. Machinability Rating Moderate to good; easier than acrylic but softer than engineering plastics like Delrin or Nylon.

Physical Properties

Property Value
Density 0.90–0.92 g/cm³
Melting Point 160–170°C
Glass Transition Temperature (Tg) –10 to 0°C
Service Temperature (Continuous) –20°C to +100°C
Tensile Strength 30–40 MPa (homopolymer), 25–35 MPa (copolymer)
Flexural Strength 40–60 MPa
Impact Strength (Notched Izod) 1.5–3 kJ/m² (homopolymer), 3–6 kJ/m² (impact copolymer)
Elongation at Break 200–600% (copolymer), 50–300% (homopolymer)
Shore D Hardness 55–65
Water Absorption (24 hrs) ~0.01%
Thermal Conductivity 0.22 W/m·K
Coefficient of Linear Expansion 10–20 × 10⁻⁵ /°C
Electrical Resistivity 10¹³–10¹⁶ Ω·cm
Flammability Self-extinguishing grades available

Chemical Properties

Property Value
Acid Resistance Excellent resistance to weak and strong acids at room temperature.
Alkali Resistance Excellent resistance to mild and strong alkalis.
Solvent Resistance Good resistance to hydrocarbons, alcohols, and ketones; limited resistance to aromatic and chlorinated solvents.
Alcohol Resistance Good; generally stable under exposure to most alcohols.
Oxidation Resistance Fair; may degrade with prolonged exposure to strong oxidizing agents.
UV Resistance Moderate; can degrade under prolonged sunlight unless UV-stabilized grades are used.
Weathering Resistance Good for indoor and short-term outdoor use; stabilized grades suitable for long-term outdoor exposure.
Hydrolysis Resistance Excellent; negligible water absorption prevents dimensional changes.
Flammability Burns slowly; self-extinguishing grades available.
Chemical Reactivity Chemically inert under normal conditions; resistant to many acids, bases, and solvents at moderate temperatures.

Dealer

We supply high-quality Polypropylene (PP) in sheets, rods, tubes, and custom-molded components suitable for industrial, automotive, and consumer applications. Material is available in homopolymer, random copolymer, and impact copolymer grades, with or without fillers and UV stabilizers. Product Forms Sheets / Plates: 1 mm to 50 mm (custom thickness available) Rods / Bars: 5 mm to 200 mm diameter Tubes / Pipes: Custom O.D. and I.D. Custom Fabrication: CNC machining, thermoforming, and injection-molded parts